Hiya,
Suther, I was just wondering out of interest, have you already completed the logic or are you starting with the basic transistors themselves?
Building any kind of electrical device is much the same as programming. Like starting with a flow chart, breaking things down into blocks and then breaking those blocks down into gates / transistors etc.
PSpice can simulate something as complex as a microprocessor (unless you're talking about something like a PDP-11), but as Candy points out - There'll be a whole lot of waiting going on.
Come to think of it, several companies in the 1970's built their own PDP-11's because they couldn't afford one. Xerox PARC (the guy's who invented all the GUI stuff) if I recall built their first one. The schematics should be out there somewhere........
http://home.alltel.net/engdahl/PDP-11.htm
Anyway, I wouldn't worry about anything physically electrical until the design works on paper. At that point you should be able to convert it to VHDL & friends.
A book I would recommend is "Computer Organisations and Design by David Patterson & John Hennessy". The book shows the design and construction of a MIPS code processor from the first adders, comparators, right through to a full implementation of the MIPS instruction set. Comparisons with different ways of implementation (performance / cost / complexity) are also made.
(MIPS Trademark, Copyright, Patented etc.... Silicon Graphics)
Compare this with say the ARM architecture or even the humble 6502 block architecture (million of C64's still runnning on that chip!)
Basically what I recommend is following a TOP-DOWN design process. What will you use your processor for?
8-Bits is good for microcontrolling, 32 a minimum for desktop.
8 Bits is easy(er) due to less circuitry, just have realistic expectations on what it will be capable of doing. Kind of like implementing a new compiler in hardware is suppose.
Only once you've got a design that meets your need can you go to the books and figure out how the stuff is implemented in hardware. Bipolar/CMOS/GAs/Bi-Cmos/SOS/SOD/TTL(If you want to build that PDP-11!)
Anyway, I'll shut up now. Hope this stirs the brain porridge.
P.S. If you already have a working logic design I humbly apologise for my rambling!